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[BioMatNet Database - FAIR Program] FAIR-CT96-3055
High performance gelatines from alternative sources
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FAIR Area 2.1 - Chemical and Physical Processes : Fine Chemicals : Fish Oil/Fat



Type of Project Shared Cost
Contract No FAIR-CT96-3055
Total Cost 1 816 571 ECU
EC Contribution 960,000 ECU
Start Date 01/09/97
Duration 36 Months

Objectives
There are several reasons for the need for gelatine from alternative sources specially in Europe as the largest companies in commercial gelatine production are found there. The world wide supply of gelatine is between 200-250 thousand tons per year and the global demand for gelatines has been estimated to increase 3% per annum. However, the consumption of meat is decreasing in Europe as well as there is an increased demand for pig skins for other uses which has resulted in decreased availability of raw material for gelatine production. But there are also opportunities to compensate for the loss as there are a great volumes of under-utilised by-products or waste material specially in the fish industry, i.e. fish skins and bones that could be used to produce gelatine instead of going to waste or low prised by-products. One of the aims of this project is to explore the feasibility to use such waste material from the fish industry and other food industries to produce gelatine and thereby help keeping the gelatine production in Europe to grow further.

The main objective of the project is to make high performance gelatines from alternative sources or from blends of commercial gelatines and gelatines from alternative sources. These gelatines from alternative sources will be studied and compared to commercial gelatines. The structural properties are to be related to functional properties. This information will be used to broaden the use of gelatines by:

Methodology and research tasks
The project is divided into three tasks. In Task 1, the variation in the structure and function of gelatines from different origins are studied with fundamental and empirical methods. The main emphasis is on the study of functional properties of the new gelatines (e.g. fish gelatines) and to relate them to their structural properties studied and finally to compare the results to commercial gelatines. The relationship between structural properties and functional properties is necessary to take into account in order to explain the performance of different gelatines. Also if predictions are to be made of the performance of gelatines in various applications. This type of work has only been done to a small extent on gelatine for historical reasons as gelatine production started without considering such relations of properties. The new gelatines can be looked upon as new biopolymers that need to be characterised thoroughly and for example 50 man years have been used for similar work on gellan gum the past years as that was thought necessary to characterise the new biopolymer to be able to put it on the market. One can argue that the same arguments count for the new gelatines.

In Task 2, blends of the new products and commercial gelatines will be prepared and evaluated. Functional performance of the blends are of special interest and their possible application as well a, potential exploitation. In the third Task, modelling of structural and functional properties will be performed based on the results from the project in order to explain our findings and to be able to predict performances of gelatines in various applications. Measurements on structural properties are performed on gelatine in solution to study coil-helix transitions and gelation i.e. sol-gel transition, both rate and quantity with methods such as optical rotation measurements, atomic force microscopy-, interfacial studies with drop volume technique, elongational flow and intrinsic viscosity measurements. Other measurements related to structure are performed like amino acid analysis, molecular weight and weight distribution, isoelectric points and more. Functional properties measured will mainly be rheological i.e. viscosity and viscoelastic properties-but also foaming ability, film forming and wetting. Performance of blends of novel gelatines and commercial gelatines will be measured and evaluated and their potential application explored. Finally both structural and statistical models will be constructed in order to explain the behaviour of different gelatines and to predict their performances in various applications and blends.

Work that has been started
The work has already started in Task 1, where 8 different samples of gelatine from- fish (cod, plaice) and mammalian from beef and pig (hides and bones) are to be studied to begin with. The gelatines are also differentiated by the production process that is either alkali or acidic and also if the gelatines are high molecular weight (MW) or low in MW. Other novel gelatines will be studied later in order to have as wide range of different gelatines representing different properties. The structural and functional measurements have been performed according to the plan set out in the contract as well as all supporting analysis. The gelatines were first prepared at the laboratories of four different partners and then send to each participant. Now the samples are analysed and measured with the methodologies as mentioned above, first in their natural state and then later were factors such as pH, ionic strength, concentration and temperature are varied.





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